"Understanding negative thermal expansion and ''trap door'' cation relocations in zeolite rho"
- Authors
B.A. Reisner, Y. Lee, J.C. Hanson, G.A. Jones, J.B. Parise, D.R. Corbin, B.H. Toby, A. Freitag, J.Z. Larese, V. Kahlenberg
- Journal
Chemical Communications
Vol.22, pp.2221-2222, 2000.10 - DOI
Abstract
In situ time-resolved synchrotron X-ray and neutron powder diffraction studies indicate that the negative thermal expansion and ‘trap door’ cation relocations observed in zeolite rho result from water-mediated chemical changes that occur during dehydration.