“Super-Hydrated Zeolites: Pressure-Induced Hydration in Natrolites”
- Authors
D. Seoung, Y. Lee, C.-C. Kao, T. Vogt, Y. Lee*
- Journal
Chemistry - A European Journal
Vol.19(33), pp.10876-10883, 2013.03 - DOI
Abstract
Zeolite under pressure: Super-hydrated zeolite, K16Al16Si24O80⋅32 H2O, undergoes a unique transformation above 2.5 GPa whereby the potassium ions interchange their locations with those of water, whereas the elliptical channel reverts its major–minor axes, resembling a “chatterbox motion” (see graphic). Alkali-metal-exchanged natrolites under pressure reveal structural changes that far exceed what can be achieved by varying temperature and chemical composition